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Composite material with EMI shielding properties and process to produce it

專利號(hào)
US11889671B2
公開日期
2024-01-30
申請人
TOTALENERGIES ONETECH; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS); UNIVERSITé CLAUDE BERNARD LYON 1 (UCBL)(FR Courbevoie FR Paris FR Villeurbanne)
發(fā)明人
Olivier Lhost; Yves Trolez; Anatoli Serghei; Hubert Lecocq; Philippe Cassagnau
IPC分類
H05K9/00; C08J3/20; C08K5/09; C08K5/20; C08K9/02
技術(shù)領(lǐng)域
wt,resin,composite,fibres,at,mi2,from,min,shielding,polymer
地域: Courbevoie

摘要

The disclosure provides for a composite material suitable for use as EMI shielding material, remarkable in that it comprises a component A being a polymer resin being at least one amorphous polymer resin and/or at least one semi-crystalline polymer resin selected from polyethylene resin and/or polypropylene resin; from 15.0 to 60.0 wt. % of component B being at least one metal-coated particle based on the total weight of the composite material; and from 0.5 to 5.0 wt. % of component C being one or more dispersants based on the total weight of the composite material; wherein one or more dispersants are selected from fatty acids, fatty acid derivatives, ethylene bis stearamide, functionalized waxes, maleic anhydride-grafted polymers and any mixture thereof; wherein the blend of components A, B and C shows a density ranging from 0.8 to 2.0 g/cc. A process to produce such composite material is also described as well as an EMI shield article made from such composite material and the use of such composite material in an EMO shield article.

說明書

The average molecular weight of the rubber, for which the intrinsic viscosity is a measure, is controlled by the addition of hydrogen to the polymerization reactors of the second polymerization stage. The amount of hydrogen added is such that the rubber has an intrinsic viscosity of at least 2.0 dl/g, and of at most 5.5 dl/g, measured in tetralin at 135° C. following ISO 1628. The contribution of the second polymerization stage, i.e. the rubber content of the heterophasic propylene copolymer is from 5 to 50 wt. % relative to the total weight of the heterophasic propylene copolymer.

After the last polymerization reactor, the polymers are recovered as a powder and can then be pelletized or granulated.

Examples of polypropylene resins suitable to be used as component A are commercially available from Total?. A non-limitative example is PPC7760 with a melt index MI2 of 15.0 g/10 min. Another example is PPH 7060 with a melt index MI2 of 12 g/10 min. Another example is PPC 6742 with a melt index MI2 of 8 g/10 min. Another example is MH140CN0, with a melt index MI2 of 140 g/10 min. All MI2 are determined according to ISO 1133 at 230° C. under a load of 2.16 kg.

For example, the at least one polypropylene resin is selected from a virgin polypropylene resin, a polypropylene post-consumer resin and a blend of a virgin polypropylene resin and a polypropylene post-consumer resin.

In one or more embodiments, the at least one polypropylene resin comprises a post-consumer polypropylene resin at a content ranging from 5 to 100 wt. % of polypropylene post-consumer resin based on the total weight of component A; for example, from 20 to 95 wt %; for example, from 40 to 90 wt. %; for example, from 50 to 85 wt. %; for example, from 60 to 80 wt %.

權(quán)利要求

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