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Composite material with EMI shielding properties and process to produce it

專利號(hào)
US11889671B2
公開日期
2024-01-30
申請(qǐng)人
TOTALENERGIES ONETECH; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS); UNIVERSITé CLAUDE BERNARD LYON 1 (UCBL)(FR Courbevoie FR Paris FR Villeurbanne)
發(fā)明人
Olivier Lhost; Yves Trolez; Anatoli Serghei; Hubert Lecocq; Philippe Cassagnau
IPC分類
H05K9/00; C08J3/20; C08K5/09; C08K5/20; C08K9/02
技術(shù)領(lǐng)域
wt,resin,composite,fibres,at,mi2,from,min,shielding,polymer
地域: Courbevoie

摘要

The disclosure provides for a composite material suitable for use as EMI shielding material, remarkable in that it comprises a component A being a polymer resin being at least one amorphous polymer resin and/or at least one semi-crystalline polymer resin selected from polyethylene resin and/or polypropylene resin; from 15.0 to 60.0 wt. % of component B being at least one metal-coated particle based on the total weight of the composite material; and from 0.5 to 5.0 wt. % of component C being one or more dispersants based on the total weight of the composite material; wherein one or more dispersants are selected from fatty acids, fatty acid derivatives, ethylene bis stearamide, functionalized waxes, maleic anhydride-grafted polymers and any mixture thereof; wherein the blend of components A, B and C shows a density ranging from 0.8 to 2.0 g/cc. A process to produce such composite material is also described as well as an EMI shield article made from such composite material and the use of such composite material in an EMO shield article.

說明書

With preference, the at least one filler is at least one reinforcement material selected from carbon black, carbon fibers, carbon nanotubes, talc mineral filler, wollastonite, calcium carbonate, modified calcium carbonate, coated calcium carbonate, glass fibres, bamboo fibres, flax fibres, hemp fibres, and any mixture thereof.

Examples of talc that can be used according to the present disclosure are talc filler Finntalc MO5SL and Finntalc M15, both manufactured and sold by Mondo Minerals (CAS-No. 14807-96-6). Finntalc MO5SL has a median particle size (d50) of 2.2 μm. Finntalc M15 has a median particle size (d50) of 4.5 μm.

For example, the at least one filler comprises at least one reinforcement material selected from talc mineral filler, wollastonite, calcium carbonate, modified calcium carbonate, coated calcium carbonate, glass fibres, bamboo fibres, flax fibres, hemp fibres, and any mixture thereof. With preference, the at least one filler is or comprises talc.

The Optional Component E being at Least One Elastomer

In a preferred embodiment, to enhance the impact properties, the composite material may comprise component E being at least one elastomer.

The component E, when present, is preferably selected from copolymers of ethylene with a C3-C10 α-olefin containing at least 20 wt %, preferably from 20 to 70 wt. %, of C3-C10 α-olefin (13C-NMR analysis). Suitable and preferred copolymers that can be used as component E commercially available are obtained with metallocene or constrained geometry catalyst and typically have molecular weight distribution (Mw/Mn measured via GPC) ranging from 1 to 3.

權(quán)利要求

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