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Composite material with EMI shielding properties and process to produce it

專利號
US11889671B2
公開日期
2024-01-30
申請人
TOTALENERGIES ONETECH; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS); UNIVERSITé CLAUDE BERNARD LYON 1 (UCBL)(FR Courbevoie FR Paris FR Villeurbanne)
發(fā)明人
Olivier Lhost; Yves Trolez; Anatoli Serghei; Hubert Lecocq; Philippe Cassagnau
IPC分類
H05K9/00; C08J3/20; C08K5/09; C08K5/20; C08K9/02
技術(shù)領(lǐng)域
wt,resin,composite,fibres,at,mi2,from,min,shielding,polymer
地域: Courbevoie

摘要

The disclosure provides for a composite material suitable for use as EMI shielding material, remarkable in that it comprises a component A being a polymer resin being at least one amorphous polymer resin and/or at least one semi-crystalline polymer resin selected from polyethylene resin and/or polypropylene resin; from 15.0 to 60.0 wt. % of component B being at least one metal-coated particle based on the total weight of the composite material; and from 0.5 to 5.0 wt. % of component C being one or more dispersants based on the total weight of the composite material; wherein one or more dispersants are selected from fatty acids, fatty acid derivatives, ethylene bis stearamide, functionalized waxes, maleic anhydride-grafted polymers and any mixture thereof; wherein the blend of components A, B and C shows a density ranging from 0.8 to 2.0 g/cc. A process to produce such composite material is also described as well as an EMI shield article made from such composite material and the use of such composite material in an EMO shield article.

說明書

Example 1: Preparation of the Composite Materials

Composite material with metal-coated particles was produced wherein:

    • Component A used was a polypropylene PPH 7060 commercially available from TOTAL?, the polypropylene is a homopolymer having an MFI of 12 g/10 min as determined by ISO1133 (230° C.?2.16 kg/10 min).
    • Component B was silver-coated glass fibres with an average length of 180 μm and an average diameter of 15 μm. The average density was 3.1 g/cc. The silver content is about 20 wt. % based on the total weight of the fibres and the silver layer is nanometric. The silver-coated glass fibres were commercially available from Hart Materials UK.
    • optional component C being stearic acid. The stearic acid used was commercially available from Sigma-Aldrich Merck France (>95% purity grade).

When component C is added, the composite material is according to the disclosure. In the absence of component C, the composite material is comparative.

Comparative composite materials were also produced wherein component A being polypropylene PPH 7060 and electrically conductive particles, alternative to component B, being metal particles. In specie, the metal particles were tin particles commercially available from GoodFellow under the reference SN006020 with an average diameter of 45 μm.

Other comparative composite materials were produced wherein component A being polypropylene PPH 7060 and electrically conductive particles, alternative to component B, being carbon nanotubes. The CNT used were Nanocyl? NC 7000 available from Nanocyl.

權(quán)利要求

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