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Composite material with EMI shielding properties and process to produce it

專利號
US11889671B2
公開日期
2024-01-30
申請人
TOTALENERGIES ONETECH; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS); UNIVERSITé CLAUDE BERNARD LYON 1 (UCBL)(FR Courbevoie FR Paris FR Villeurbanne)
發(fā)明人
Olivier Lhost; Yves Trolez; Anatoli Serghei; Hubert Lecocq; Philippe Cassagnau
IPC分類
H05K9/00; C08J3/20; C08K5/09; C08K5/20; C08K9/02
技術領域
wt,resin,composite,fibres,at,mi2,from,min,shielding,polymer
地域: Courbevoie

摘要

The disclosure provides for a composite material suitable for use as EMI shielding material, remarkable in that it comprises a component A being a polymer resin being at least one amorphous polymer resin and/or at least one semi-crystalline polymer resin selected from polyethylene resin and/or polypropylene resin; from 15.0 to 60.0 wt. % of component B being at least one metal-coated particle based on the total weight of the composite material; and from 0.5 to 5.0 wt. % of component C being one or more dispersants based on the total weight of the composite material; wherein one or more dispersants are selected from fatty acids, fatty acid derivatives, ethylene bis stearamide, functionalized waxes, maleic anhydride-grafted polymers and any mixture thereof; wherein the blend of components A, B and C shows a density ranging from 0.8 to 2.0 g/cc. A process to produce such composite material is also described as well as an EMI shield article made from such composite material and the use of such composite material in an EMO shield article.

說明書

From the results, it can be seen that the best compromise between the EMI shielding and the density is achieved by the composite material containing silver glass fibres in the presence of stearic acid. With carbon nanotubes composites, even if composites densities remain decent, a shielding of 40 dB at 1 mm thickness was never surpassed without important drawbacks in processing and composite mechanical properties. The improvement of shielding properties in the presence of stearic acid for silver glass fiber composites was unexpected since, for carbon nanotubes, the addition of stearic acid brought no improvement of composite electromagnetic shielding properties (see S5 and S6). Comparing S1 and S2 it can be seen that at a similar filler volume concentration, the silver glass fibre composites display shielding values superior to 40 dB in the presence of stearic acid at 1 mm thickness, and the composites densities remain interesting. Tin composites display interesting shielding at 2 mm thickness but the density of the resulting composite is too high and involves an increase of the weight for the products made from the composite, which goes against the concern of lightening the weight of the vehicles to limit the production of greenhouse gases when they are driven.

Example 2: Effect of Stearic Acid (Component C) on the Electromagnetic Shielding

Several composite materials being polypropylene-based composite material containing silver glass fibres were produced with different content of metal-coated particles (component B) and/or with different content of dispersant (i.e. component C).

The samples are polypropylene-based composite material prepared in the absence of acid stearic or the presence of acid stearic using the process of example 1. The mixing was done at 50 rpm.

權利要求

1
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