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Composite material with EMI shielding properties and process to produce it

專利號(hào)
US11889671B2
公開日期
2024-01-30
申請(qǐng)人
TOTALENERGIES ONETECH; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS); UNIVERSITé CLAUDE BERNARD LYON 1 (UCBL)(FR Courbevoie FR Paris FR Villeurbanne)
發(fā)明人
Olivier Lhost; Yves Trolez; Anatoli Serghei; Hubert Lecocq; Philippe Cassagnau
IPC分類
H05K9/00; C08J3/20; C08K5/09; C08K5/20; C08K9/02
技術(shù)領(lǐng)域
wt,resin,composite,fibres,at,mi2,from,min,shielding,polymer
地域: Courbevoie

摘要

The disclosure provides for a composite material suitable for use as EMI shielding material, remarkable in that it comprises a component A being a polymer resin being at least one amorphous polymer resin and/or at least one semi-crystalline polymer resin selected from polyethylene resin and/or polypropylene resin; from 15.0 to 60.0 wt. % of component B being at least one metal-coated particle based on the total weight of the composite material; and from 0.5 to 5.0 wt. % of component C being one or more dispersants based on the total weight of the composite material; wherein one or more dispersants are selected from fatty acids, fatty acid derivatives, ethylene bis stearamide, functionalized waxes, maleic anhydride-grafted polymers and any mixture thereof; wherein the blend of components A, B and C shows a density ranging from 0.8 to 2.0 g/cc. A process to produce such composite material is also described as well as an EMI shield article made from such composite material and the use of such composite material in an EMO shield article.

說明書

From the results, it can be seen that the shielding increases with the content of stearic acid up to about 2 vol. % of stearic acid (i.e. about 2 wt. %) and then start to decrease. The optimised range is, therefore, ranging from 1.5 to 4.0 wt. % of component C based on the total weight of the composite material, with preference from 1.5 to 3.0 wt. %.

Example 3: Effect of Stearic Acid (Component C) on the Percolation Threshold and the Electrical Conductivity

The percolation threshold of the different electrically conductive fillers was studied in the absence or the presence of stearic acid. The results in the absence of stearic acid are reported in FIG. 8. From this figure, it can further be seen that the metal-coated particles tested (i.e. silver glass fibres) provide an electrical conductivity that is similar to the metal particle (i.e. tin particles) but with a lower percolation threshold. The carbon particle (i.e. CNT) shows lower electrical conductivity.

FIG. 9 shows the effect of the presence of stearic acid on the electrical conductivity of the composite material containing silver glass fibres. It can be seen that the percolation threshold is lowered and at the same time the electrical conductivity is enhanced. Since stearic acid has no properties of electrical conduction a synergetic effect is therefore shown. The same effect was observed with tin particles but not with the CNT, suggesting that the synergetic effect occurs with metal or metal-coated particles only.

Example 4: Mechanical Properties

Traction tests were performed on Injected PP AgGF 10 vol. %, stearic acid 2 vol. %. Composite made in internal mixer 200° C., 100 rpm.

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