A method and apparatus for discovering and selecting a network that provides connectivity for transmitting user subscription data is provided. A user equipment (UE) in a wireless communication system includes a transceiver and at least one processor configured to identify preconfigured first information comprising a first list, the first list comprising at least one identifier (ID) of at least one network group providing an initial access to a non-public network (NPN), receive, from at least one base station via the transceiver, second information comprising at least one second list, the at least one second list comprising at least one ID of at least one network group which is supported by the at least one base station and provides an initial access to the NPN, and select a network to be initially accessed from a network group corresponding to at least one ID included in the first list and the at least one second list, based on the first information and the second information.