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Coin-shaped lithium secondary battery and IoT device

專利號
US11996544B2
公開日期
2024-05-28
申請人
NGK INSULATORS, LTD.(JP Nagoya)
發(fā)明人
Yukinobu Yura; Kazuki Maeda; Shunsuke Mizukami
IPC分類
H01M4/131; H01M4/02; H01M4/04; H01M4/134; H01M4/525; H01M4/66; H01M10/0525; H01M50/409; H01M50/429; H01M50/44; H01M50/46
技術(shù)領(lǐng)域
electrode,plate,lto,lco,sintered,lithium,positive,sheet,battery,green
地域: Nagoya

摘要

Provided is a coin-shaped lithium secondary battery including a positive electrode plate which is a lithium complex oxide sintered plate; a negative electrode plate which is a titanium-containing sintered plate; a separator interposed between the positive electrode plate and the negative electrode plate; an electrolytic solution with which the positive electrode plate, the negative electrode, and the separator are impregnated; and an exterior body having a closed space, the closed space accommodating the positive electrode plate, the negative electrode plate, the separator, and the electrolytic solution, the lithium secondary battery having a thickness of 0.7 to 1.6 mm and a diameter of 10 to 20 mm.

說明書

The positive electrode plate 12, that is, the lithium complex oxide sintered plate preferably has a porosity of 20 to 60%, more preferably 25 to 55%, further preferably 30 to 50%, particularly preferably 30 to 45%. The stress relief effect by the pores and the increase in capacity can be expected, and the mutual adhesion between the primary grains 11 can be further improved, so that the rate characteristics can be further improved. The porosity of the sintered body is calculated by polishing a cross section of the positive electrode plate with CP (cross-section polisher) polishing, thereafter observing the cross section at a magnification of 1000 times with SEM, and binarizing the SEM image obtained. The average equivalent circle diameter of pores formed inside the oriented sintered body is not particularly limited but is preferably 8 μm or less. The smaller the average equivalent circle diameter of the pores, the mutual adhesion between the primary grains 11 can be improved more. As a result, the rate characteristic can be improved more. The average equivalent circle diameter of the pores is a value obtained by arithmetically averaging the equivalent circle diameters of 10 pores on the EBSD image. An equivalent circle diameter is the diameter of a circle having the same area as each pore on the EBSD image. Each of the pores formed inside the oriented sintered body is preferably an open pore connected to the outside of the positive electrode plate 12.

The positive electrode plate 12, that is, the lithium complex oxide sintered plate preferably has a mean pore diameter of 0.1 to 10.0 μm, more preferably 0.2 to 5.0 μm, further preferably 0.3 to 3.0 μm. Within such a range, stress concentration is suppressed from occurring locally in large pores, and the stress is easily released uniformly in the sintered body.

權(quán)利要求

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