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Coin-shaped lithium secondary battery and IoT device

專利號
US11996544B2
公開日期
2024-05-28
申請人
NGK INSULATORS, LTD.(JP Nagoya)
發(fā)明人
Yukinobu Yura; Kazuki Maeda; Shunsuke Mizukami
IPC分類
H01M4/131; H01M4/02; H01M4/04; H01M4/134; H01M4/525; H01M4/66; H01M10/0525; H01M50/409; H01M50/429; H01M50/44; H01M50/46
技術(shù)領(lǐng)域
electrode,plate,lto,lco,sintered,lithium,positive,sheet,battery,green
地域: Nagoya

摘要

Provided is a coin-shaped lithium secondary battery including a positive electrode plate which is a lithium complex oxide sintered plate; a negative electrode plate which is a titanium-containing sintered plate; a separator interposed between the positive electrode plate and the negative electrode plate; an electrolytic solution with which the positive electrode plate, the negative electrode, and the separator are impregnated; and an exterior body having a closed space, the closed space accommodating the positive electrode plate, the negative electrode plate, the separator, and the electrolytic solution, the lithium secondary battery having a thickness of 0.7 to 1.6 mm and a diameter of 10 to 20 mm.

說明書

The negative electrode plate 16, that is, the titanium-containing sintered plate has a structure that a plurality (namely, a large number) of primary grains are bonded. Accordingly, these primary grains are preferably composed of LTO or Nb2TiO7.

The negative electrode plate 16 preferably has a thickness of 70 to 500 μm, preferably 85 to 400 μm, more preferably 95 to 350 μm. The larger the thickness of the LTO sintered plate, a battery with high capacity and high energy density is achieved more easily. The thickness of the negative electrode plate 16 is determined by measuring the distance between the two substantially parallel faces of the plate, for example, when the cross section of the negative electrode plate 16 is observed by SEM (scanning electron microscopy).

The primary grain size that is the average grain size of the plurality of primary grains forming the negative electrode plate 16 is preferably 1.2 μm or less, more preferably 0.02 to 1.2 μm, further preferably 0.05 to 0.7 μm. Within such a range, the lithium ion conductivity and the electron conductivity are easily compatible with each other, which contributes to improving the rate performance.

The negative electrode plate 16 preferably contains pores. The electrolytic solution can penetrate into the sintered plate by the sintered plate including pores, particularly open pores, when the sintered plate is integrated into a battery as a negative electrode plate. As a result, the lithium ion conductivity can be improved. This is because there are two types of conduction of lithium ions within the sintered body: conduction through constituent grains of the sintered body; and conduction through the electrolytic solution within the pores, and the conduction through the electrolytic solution within the pores is overwhelmingly faster.

權(quán)利要求

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