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Coin-shaped lithium secondary battery and IoT device

專(zhuān)利號(hào)
US11996544B2
公開(kāi)日期
2024-05-28
申請(qǐng)人
NGK INSULATORS, LTD.(JP Nagoya)
發(fā)明人
Yukinobu Yura; Kazuki Maeda; Shunsuke Mizukami
IPC分類(lèi)
H01M4/131; H01M4/02; H01M4/04; H01M4/134; H01M4/525; H01M4/66; H01M10/0525; H01M50/409; H01M50/429; H01M50/44; H01M50/46
技術(shù)領(lǐng)域
electrode,plate,lto,lco,sintered,lithium,positive,sheet,battery,green
地域: Nagoya

摘要

Provided is a coin-shaped lithium secondary battery including a positive electrode plate which is a lithium complex oxide sintered plate; a negative electrode plate which is a titanium-containing sintered plate; a separator interposed between the positive electrode plate and the negative electrode plate; an electrolytic solution with which the positive electrode plate, the negative electrode, and the separator are impregnated; and an exterior body having a closed space, the closed space accommodating the positive electrode plate, the negative electrode plate, the separator, and the electrolytic solution, the lithium secondary battery having a thickness of 0.7 to 1.6 mm and a diameter of 10 to 20 mm.

說(shuō)明書(shū)

Meanwhile, such powder-dispersed positive electrodes generally contain a relatively large amount (e.g., about 10% by weight) of components (binders and conductive agents) that do not contribute to the capacity of battery, resulting in a low packing density of the positive electrode active material, i.e., lithium complex oxide. Accordingly, the powder-dispersed positive electrode should be greatly improved from the viewpoint of the capacity and charge/discharge efficiency. Some attempts have been made to improve the capacity and charge/discharge efficiency by positive electrodes or layers of positive electrode active material composed of lithium complex oxide sintered plate. In this case, since the positive electrode or the layer of positive electrode active material contains no binder or conductive agent, high capacity and satisfactory charge/discharge efficiency can be expected due to a high packing density of lithium complex oxide. For example, Patent Literature 4 (JP5587052B) discloses a positive electrode including a positive electrode current collector and a positive electrode active material layer connected to the positive electrode current collector with a conductive bonding layer therebetween. The positive electrode active material layer is composed of a lithium complex oxide sintered plate, and the sintered plate has a thickness of 30 μm or more, a porosity of 3 to 30%, and an open pore rate of 70% or more. Further, Patent Literature 5 (WO2017/146088) discloses use of an oriented sintered plate including a plurality of primary grains composed of lithium complex oxide such as lithium cobaltate (LiCoO2), the plurality of primary grains being oriented at an average orientation angle of over 0° and 30° or less to the plate face in the positive electrode plate, as a positive electrode of a lithium secondary battery including a solid electrolyte.

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