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Coin-shaped lithium secondary battery and IoT device

專利號
US11996544B2
公開日期
2024-05-28
申請人
NGK INSULATORS, LTD.(JP Nagoya)
發(fā)明人
Yukinobu Yura; Kazuki Maeda; Shunsuke Mizukami
IPC分類
H01M4/131; H01M4/02; H01M4/04; H01M4/134; H01M4/525; H01M4/66; H01M10/0525; H01M50/409; H01M50/429; H01M50/44; H01M50/46
技術(shù)領(lǐng)域
electrode,plate,lto,lco,sintered,lithium,positive,sheet,battery,green
地域: Nagoya

摘要

Provided is a coin-shaped lithium secondary battery including a positive electrode plate which is a lithium complex oxide sintered plate; a negative electrode plate which is a titanium-containing sintered plate; a separator interposed between the positive electrode plate and the negative electrode plate; an electrolytic solution with which the positive electrode plate, the negative electrode, and the separator are impregnated; and an exterior body having a closed space, the closed space accommodating the positive electrode plate, the negative electrode plate, the separator, and the electrolytic solution, the lithium secondary battery having a thickness of 0.7 to 1.6 mm and a diameter of 10 to 20 mm.

說明書

The LCO sintered plate was polished with a cross section polisher (CP) (IB-15000CP, manufactured by JEOL Ltd.), and the resultant cross-section of the positive electrode plate (cross-section perpendicular to the plate face of the positive electrode plate) was subjected to the EBSD measurement at a 1000-fold field of view (125 μm×125 μm) to give an EBSD image. This EBSD measurement was performed using a Schottky field emission scanning electron microscope (model JSM-7800F, manufactured by JEOL Ltd.). For all grains identified in the resultant EBSD image, the angles defined by the (003) planes of the primary grains and the plate face of the positive electrode plate (that is, the tilt of the crystal orientation from the (003) planes) is determined as a tilt angle. The mean value of the angles was determined as an average orientation angle of the primary grains.

<Thickness>

The LCO or LTO sintered plate was polished with a cross-section polisher (CP) (IB-15000CP, manufactured by JEOL Ltd.), and the resultant cross section of the positive electrode plate was observed with SEM (JSM6390LA, manufactured by JEOL Ltd.) to determine the thickness of the positive electrode plate. The thickness of the dried LCO or LTO green sheet described above in Procedures (1a) and (2a) was also determined in the same manner.

<Porosity>

The LCO or LTO sintered plate was polished with a cross-section polisher (CP) (IB-15000CP, manufactured by JEOL Ltd.), and the resultant cross section of the positive electrode plate was observed with SEM (JSM6390LA, manufactured by JEOL Ltd.) at a 1000-fold field of view (125 μm×125 μm). The SEM image was subjected to an image analysis, the area of all pores was divided by the area of the positive electrode, and the resultant value was multiplied by 100 to calculate the porosity (%).

權(quán)利要求

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