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Method of coating electroactive materials with conductive polymers

專利號(hào)
US11996553B2
公開日期
2024-05-28
申請(qǐng)人
GM GLOBAL TECHNOLOGY OPERATIONS LLC(US MI Detroit)
發(fā)明人
Gongshin Qi; Jiazhi Hu
IPC分類
H01M4/36; H01M4/04; H01M4/38; H01M4/525; H01M4/583; H01M4/62; H01M10/0525; H01M4/02
技術(shù)領(lǐng)域
equal,lithium,or,about,optionally,electrode,than,percent,conductive,weight
地域: MI MI Detroit

摘要

The present disclosure provides a method of preparing a coated electroactive material. The method includes providing a plurality of particles including an electroactive material. The method further includes coating the plurality of particles with a conductive polymer. The coating includes preparing a solution of water and the conductive polymer. The coating further includes forming a slurry by combining the solution with the plurality of particles. The method further includes drying the slurry to form the coated electroactive material. The coated electroactive material includes the plurality of particles. Each of the plurality of particles is at least partially coated with the conductive polymer. In certain aspects, the present disclosure provides a method of preparing an electrode including the coated electroactive material.

說明書

Furthermore, the porous separator 26 may be mixed with a ceramic material or its surface may be coated in a ceramic material. For example, a ceramic coating may include alumina (Al2O3), silicon dioxide (SiO2), or combinations thereof. Various conventionally available polymers and commercial products for forming the separator 26 are contemplated, as well as the many manufacturing methods that may be employed to produce such a microporous polymer separator 26.

Solid-State Electrolyte

In various aspects, the porous separator 26 and the electrolyte 30 may be replaced with a solid state electrolyte (SSE) that functions as both an electrolyte and a separator. The SSE may be disposed between a positive electrode and a negative electrode. The SSE facilitates transfer of lithium ions, while mechanically separating and providing electrical insulation between the negative and positive electrodes 22, 24. By way of non-limiting example, SSEs may include LiTi2(PO4)3, Li1.3Al0.3Ti1.7(PO4)3 (LATP), LiGe2(PO4)3, Li7La3Zr2O12, Li3XLa2/3-xTiO3, Li3PO4, Li3N, Li4GeS4, Li10GeP2S12, Li2S—P2S5, Li6PS5Cl, Li6PS5Br, Li6PS5I, Li3OCl, Li2.99Ba0.005ClO, or combinations thereof.

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