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Method of coating electroactive materials with conductive polymers

專利號(hào)
US11996553B2
公開(kāi)日期
2024-05-28
申請(qǐng)人
GM GLOBAL TECHNOLOGY OPERATIONS LLC(US MI Detroit)
發(fā)明人
Gongshin Qi; Jiazhi Hu
IPC分類
H01M4/36; H01M4/04; H01M4/38; H01M4/525; H01M4/583; H01M4/62; H01M10/0525; H01M4/02
技術(shù)領(lǐng)域
equal,lithium,or,about,optionally,electrode,than,percent,conductive,weight
地域: MI MI Detroit

摘要

The present disclosure provides a method of preparing a coated electroactive material. The method includes providing a plurality of particles including an electroactive material. The method further includes coating the plurality of particles with a conductive polymer. The coating includes preparing a solution of water and the conductive polymer. The coating further includes forming a slurry by combining the solution with the plurality of particles. The method further includes drying the slurry to form the coated electroactive material. The coated electroactive material includes the plurality of particles. Each of the plurality of particles is at least partially coated with the conductive polymer. In certain aspects, the present disclosure provides a method of preparing an electrode including the coated electroactive material.

說(shuō)明書

Two exemplary common classes of known electroactive materials that can be used to form the positive electrode 24 are lithium transition metal oxides with layered structures and lithium transition metal oxides with spinel phase. For example, in certain instances, the positive electrode 24 may include a spinel-type transition metal oxide, like lithium manganese oxide (Li(1+x)Mn(2?x)O4), where x is typically <0.15, including LiMn2O4 (“LMO”) and lithium manganese nickel oxide LiMn1.5Ni0.5O4 (“ ”). In other instances, the positive electrode 24 may include layered materials like lithium cobalt oxide (LiCoO2), lithium nickel oxide (LiNiO2), a lithium nickel manganese cobalt oxide (Li(NixMnyCoz)O2), where 0≤x≤1, 0≤y≤1, 0≤z≤1, and x+y+z=1 (e.g., LiNi0.6Mn0.2Co0.2O2, LiNi0.7Mn0.2Co0.1O2, LiNi0.8Mn0.1Co0.1O2, and/or LiMn0.33Ni0.33Co0.33O2), a lithium nickel cobalt metal oxide (LiNi(1?x?y)CoxMyO2), where 0<x<1, 0<y<1 and M may be Al, Mg, Mn, or the like. Other known lithium-transition metal compounds such as lithium iron phosphate (LiFePO4), lithium iron fluorophosphate (Li2FePO4F), or lithium Manganese iron phosphate (LiMnFePO4) can also be used. In certain aspects, the positive electrode 24 may include an electroactive material that includes manganese, such as lithium manganese oxide (Li(1+x)Mn(2?x)O4), and/or a mixed lithium manganese nickel oxide (LiMn(2?x)NixO4), where 0≤x≤1. In a lithium-sulfur battery, positive electrodes may have elemental sulfur as the active material or a sulfur-containing active material.

權(quán)利要求

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