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Positive electrode material of lithium-ion battery and preparation method therefor

專利號(hào)
US11996560B1
公開(kāi)日期
2024-05-28
申請(qǐng)人
Beijing Easpring Material Technology Co., Ltd.(CN Beijing)
發(fā)明人
Junfan Tong; Yanbin Chen; Yuqiang Jin; Wenbo Wang; Xuequan Zhang; Yafei Liu
IPC分類
H01M4/00; C01G53/00; H01M4/131; H01M4/505; H01M4/525; H01M10/0525
技術(shù)領(lǐng)域
calcining,electrode,positive,manganese,cobalt,dopant,material,nickel,lithium,in
地域: Beijing

摘要

The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

說(shuō)明書

The positive electrode material in accordance with the present disclosure is obtained by subjecting the nickel cobalt manganese active material to doping and lithiating, which involve the step of programmed calcining, to obtain higher particle strength. Without intending to be bond to any theory, it is believed that dopant elements may be partially incorporated into the skeleton of the particles, stabilizing the lattice structure and thereby increasing the strength of the particles. At the same time, if there is a coating layer, it can inhibit or alleviate the interfacial reaction between the positive electrode material and electrolyte, thereby inhibiting or alleviating the corrosion of the positive electrode material by electrolyte. More importantly, the doped nickel cobalt manganese active material forms the skeleton of the positive electrode material. It makes the positive electrode material in accordance with the present disclosure have an intrinsic specific surface area and an intrinsic pore size within the required ranges. Accordingly, even after multiple battery cyclings, controlled pore configuration may be maintained. Such positive electrode material may have the characteristics of good rate performance and good cycling stability.

In a preferred embodiment, in the formula of the nickel cobalt manganese active material, 0.6≤x≤0.94, 0.03≤y≤0.2, 0.03≤z≤0.2.

In one embodiment, the doped nickel cobalt manganese active material may have a formula of Li1+a (NixCoyMnzMdGeTf) O2, wherein 0≤a≤0.1, 0.3≤x≤0.99, 0.01≤y≤0.5, 0.01≤z≤0.5, 0≤d≤0.08, 0≤e≤0.05, 0≤f≤0.03, 1≤e/f≤5, and x+y+z+d+e+f=1.

In another aspect, provided in the present disclosure is a method for preparing the above positive electrode material, comprising:

    權(quán)利要求

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