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Positive electrode material of lithium-ion battery and preparation method therefor

專利號(hào)
US11996560B1
公開日期
2024-05-28
申請(qǐng)人
Beijing Easpring Material Technology Co., Ltd.(CN Beijing)
發(fā)明人
Junfan Tong; Yanbin Chen; Yuqiang Jin; Wenbo Wang; Xuequan Zhang; Yafei Liu
IPC分類
H01M4/00; C01G53/00; H01M4/131; H01M4/505; H01M4/525; H01M10/0525
技術(shù)領(lǐng)域
calcining,electrode,positive,manganese,cobalt,dopant,material,nickel,lithium,in
地域: Beijing

摘要

The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

說明書

In one embodiment, the nickel salts, cobalt salts and manganese salts are used in a form of solution. Based on the corresponding metal elements, the solution may have a concentration of 0.01-5 mol/L, preferably 0.5-3 mol/L, more preferably 1-2 mol/L, for example, 0.01 mol/L, 0.1 mol/L, 0.5 mol/L, 1 mol/L, 2 mol/L, 3 mol/L, 4 mol/L and 5 mol/L.

The co-deposing may be operated in the presence of a solution of precipitants and a solution of complexing agents. Preferably, the co-deposing may be operated in a continuous manner.

In one embodiment, the precipitants may be at least one selected from a group consisting of NaOH, KOH and LiOH. Preferably, the solution of precipitants may have a concentration of 0.02-10 mol/L, for example, 0.05 mol/L, 0.1 mol/L, 0.5 mol/L, about 1 mol/L, 5 mol/L or 10 mol/L.

The complexing agents may be any compound capable of forming a complex with Ni, Co, and Mn from the nickel salts, cobalt salts and manganese salts in an aqueous solution. In one embodiment, the complexing agents may be at least one selected from a group consisting of ammonium ion donors, ethanolamine based complexing agents, and carboxylate based complexing agents. Preferably, the complexing agents are ammonium ion donors, preferably at least one selected from a group consisting of ammonia, ammonium oxalate, ammonium carbonate and ammonium hydroxide, more preferably ammonia. In one variant, the solution of complexing agents may have a concentration of 0.01-15 mol/L, for example, 0.01 mol/L, 0.1 mol/L, 0.5 mol/L, 1 mol/L, 5 mol/L, 10 mol/L or 15 mol/L.

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