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Positive electrode material of lithium-ion battery and preparation method therefor

專利號(hào)
US11996560B1
公開(kāi)日期
2024-05-28
申請(qǐng)人
Beijing Easpring Material Technology Co., Ltd.(CN Beijing)
發(fā)明人
Junfan Tong; Yanbin Chen; Yuqiang Jin; Wenbo Wang; Xuequan Zhang; Yafei Liu
IPC分類
H01M4/00; C01G53/00; H01M4/131; H01M4/505; H01M4/525; H01M10/0525
技術(shù)領(lǐng)域
calcining,electrode,positive,manganese,cobalt,dopant,material,nickel,lithium,in
地域: Beijing

摘要

The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

說(shuō)明書(shū)

Nickel sulfate, cobalt sulfate and manganese sulfate were dissolved in water in a molar ratio of 90:6:4 to form a 2 mol/L solution of mixed salts. A 8 mol/L solution of sodium hydroxide was used as the solution of precipitants. A 6 mol/L solution of ammonia was used as the solution of complexing agents. The solution of mixed salts, the solution of precipitants and the solution of complexing agents were fed into an autoclave respectively, with their feeding rates being controlled to achieve a reaction temperature of 60° C., pH of 11.3, and an ammonia concentration of 6 g/L. Co-deposing was operated at a stirring speed of 600 rpm. After 80 hours of the reaction, obtained was a precursor of the nickel cobalt manganese active materials. The precursor of the nickel cobalt manganese active materials was subjected to aging, separating, washing and drying, then ready for use.

(2) The Preparation of a Doped Nickel Cobalt Manganese Active Material.

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