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Positive electrode material of lithium-ion battery and preparation method therefor

專利號
US11996560B1
公開日期
2024-05-28
申請人
Beijing Easpring Material Technology Co., Ltd.(CN Beijing)
發(fā)明人
Junfan Tong; Yanbin Chen; Yuqiang Jin; Wenbo Wang; Xuequan Zhang; Yafei Liu
IPC分類
H01M4/00; C01G53/00; H01M4/131; H01M4/505; H01M4/525; H01M10/0525
技術(shù)領域
calcining,electrode,positive,manganese,cobalt,dopant,material,nickel,lithium,in
地域: Beijing

摘要

The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

說明書

The intrinsic specific surface area and intrinsic pore size of the above positive electrode material are measured after removing free substances on the surface of the tested material and even some substances inside the tested material via the extreme water washing. Upon the intrinsic specific surface area and intrinsic pore size being within the required ranges, it indicates that, even after prolonged battery cycling, the positive electrode material in accordance with the present disclosure may still have controlled pore configuration. This means that, even after prolonged operation, the positive electrode material in accordance with the present disclosure can still provide a transference path with suitable length for transferring lithium ions, avoiding loss in capacity and rate performance caused by long transference paths. At the same time, a certain ability to resist electrolyte erosion is kept, avoiding a large number of side reactions.

The lithium battery using the positive electrode material may have a discharge capacity of up to 223.8 mAh/g at a rate of 0.1 C and a capacity retention of up to 93.6% after 80 cycles at a rate of 1 C.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings in the disclosure are only intended to illustrate selected embodiments rather than all possible embodiments and are not intended to limit the scope of the disclosure.

FIG. 1 is a schematic view showing SEM images of the positive electrode material P1 obtained in Example 1-1 before and after the extreme water washing; and

FIG. 2 is a schematic view showing XRD patterns of the positive electrode material P1 obtained in Example 1-1 before and after the extreme water washing.

權(quán)利要求

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