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Positive electrode material of lithium-ion battery and preparation method therefor

專(zhuān)利號(hào)
US11996560B1
公開(kāi)日期
2024-05-28
申請(qǐng)人
Beijing Easpring Material Technology Co., Ltd.(CN Beijing)
發(fā)明人
Junfan Tong; Yanbin Chen; Yuqiang Jin; Wenbo Wang; Xuequan Zhang; Yafei Liu
IPC分類(lèi)
H01M4/00; C01G53/00; H01M4/131; H01M4/505; H01M4/525; H01M10/0525
技術(shù)領(lǐng)域
calcining,electrode,positive,manganese,cobalt,dopant,material,nickel,lithium,in
地域: Beijing

摘要

The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

說(shuō)明書(shū)

As shown in the above examples, compared to Examples 1-1 and 1-2, Comparative Example 1-1 changed the used dopant elements. Correspondingly, the positive electrode material obtained in Comparative Example 1-1 had an intrinsic specific surface area and an intrinsic pore distribution (R10, R50 and R90) both greater than those of the positive electrode materials in Examples 1-1 and 1-2. Correspondingly, it had a decreased cycle performance, with a capacity retention of only 88.6% after 80 cycles. At the same time, the positive electrode material obtained in Comparative Example 1-1 did not have a layered structure with sufficient ion stability, which made it easier to form cracks at grain boundaries, leading to a significant decrease in compressive strength. Therefore, although it had relatively good initial cycling capacity, it had degraded cycle performance at high current rates. Although Comparative example 1-2 involved the same dopant systems as those of Example 1-1 and Example 1-2, it used too low temperatures for the steps of calcining. It led to formation of incomplete crystal phases, poor construction of channels for transferring Li+, low Li+ transference number, and insufficient utilization of capacity. Comparative Example 1-3 used a reduced oxygen flow rate, leading to longer calcining time and slower oxidation. It resulted in severe Li/Ni disordering, easier formation of cracks at grain boundaries, and a decrease in compressive strength. At the same time, the transferring of Li+ was hindered. In this regard, although the initial capacity was normal, Li+ could not effectively return to its original position, leading to a decrease in both rate performance and cycle performance. When comparing Examples 2-1 and 2-2 with Comparative Examples 2-1 to 2-3, the results were consistent with the above.

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