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Positive electrode material of lithium-ion battery and preparation method therefor

專利號
US11996560B1
公開日期
2024-05-28
申請人
Beijing Easpring Material Technology Co., Ltd.(CN Beijing)
發(fā)明人
Junfan Tong; Yanbin Chen; Yuqiang Jin; Wenbo Wang; Xuequan Zhang; Yafei Liu
IPC分類
H01M4/00; C01G53/00; H01M4/131; H01M4/505; H01M4/525; H01M10/0525
技術領域
calcining,electrode,positive,manganese,cobalt,dopant,material,nickel,lithium,in
地域: Beijing

摘要

The present disclosure relates to a positive electrode material for a lithium ion battery and its preparation. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area of 5-13 m2/g. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges. In this regard, the positive electrode material in accordance with the present disclosure has excellent particle strength, excellent Li ion transference ability, and good resistance to electrolyte erosion. When used in lithium batteries, it may impart the batteries with excellent rate performance and cycle performance. The present disclosure also relates to a method for preparing the positive electrode material.

說明書

The intrinsic specific surface area and the intrinsic pore size are measured after removing free substances on the surface of the tested material and even some substances inside the tested material via the extreme water washing. When in a battery, the tested material (the positive electrode material) may contact with electrolyte, which may lead to similar extraction of substances. Therefore, the extreme water washing can be regarded as a simulation of long-term operation of positive electrode materials. In this regard, the intrinsic specific surface area and the intrinsic pore size may truly reflect the properties of the tested material after long-term cycling, especially the particle strength and the binding strength of Li ions therein. The positive electrode material in accordance with the present disclosure has an intrinsic specific surface area and an intrinsic pore size within the required ranges, indicating that, even after prolonged battery cycling, the positive electrode material in accordance with the present disclosure may still have controlled pore configuration. This means that, even after prolonged operation, the positive electrode material in accordance with the present disclosure can still provide a transference path with suitable length for transferring lithium ions, avoiding loss in capacity and rate performance caused by long transference paths. At the same time, a certain ability to resist electrolyte erosion is kept, avoiding a large number of side reactions.

In a preferred embodiment, the positive electrode material has D50 of 7.8-14.2 nm.

In a preferred embodiment, the positive electrode material has a compacted density of 2.0-3.8 g/cm3.

權利要求

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