Organic electroluminescent device comprising two-dimensional emissive layer
地域：
MI
MI Ann Arbor
摘要
An organic light emitting device comprises an anode and a cathode, at least one organic layer configured between the anode and the cathode, and at least one two-dimensional emissive layer configured between the anode and the cathode. A method of fabricating an organic light emitting device is also disclosed.
說明書
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This application claims priority to U.S. Provisional Application No. 63/043,560, filed on Jun. 24, 2020, and U.S. Provisional Application No. 63/060,393, filed on Aug. 3, 2020, both of which are incorporated herein by reference in their entireties.
This invention was made with government support under Grant Number FA9550-17-1-0208, awarded by the Air Force Office of Scientific Research, and Grant Number W911NF-17-1-0312, awarded by the U.S. Army Research Office. The government has certain rights in the invention.
權利要求
What is claimed is:1. An organic light emitting device comprising:an anode and a cathode; at least one organic charge transport layer positioned between the anode and the cathode; an organic host layer positioned between the anode and the cathode; and at least one two-dimensional emissive layer positioned at a distance of less than 10 nm from a position with the highest density of excitons within the organic host layer. 2. The organic light emitting device of claim 1 , wherein the two-dimensional emissive layer is selected from the group consisting of a transition metal dichalcogenide (TMD) active layer and a direct bandgap inorganic semiconductor. 3. The organic light emitting device of claim 2 , wherein the two-dimensional emissive layer comprises a material selected from Gallium Nitride, a group III-V direct bandgap semiconducting alloy or alloys, a group II-VI direct bandgap semiconducting alloy or alloys, or at least one monolayer of WS2. 4. The organic light emitting device of claim 1 , wherein the at least one organic charge transport layer comprises first and second organic buffer layers, and the at least one two-dimensional emissive layer is embedded between the first and second organic buffer layers. 5. The organic light emitting device of claim 4 , wherein the first organic buffer layer is a hole-transporting layer configured between the at least two-dimensional emissive layer and the anode. 6. The organic light emitting device of claim 5 , wherein the hole-transporting layer comprises 1,1-Bis[(di-4-tolylamino)phenyl]cyclohexane. 7. The organic light emitting device of claim 4 , wherein the second organic buffer layer is an electron transport layer configured between the cathode and the at least one two-dimensional emissive layer. 8. The organic light emitting device of claim 7 , wherein the electron transport layer comprises 4,6-Bis(3,5-di(pyridin-3-yl)phenyl)-2-methylpyrimidine or 4,6-Bis(3,5-di-3-pyridinylphenyl)-2-methylpyrimidine. 9. The organic light emitting device of claim 1 , wherein the organic host layer comprises 4,4′-Bis(N-carbazolyl)-1,1′-biphenyl. 10. A method of fabricating the organic light emitting device of claim 1 comprising the step of:depositing the two-dimensional emissive layer using chemical-vapor-deposition. 11. A consumer product comprising the organic light emitting device of claim 1 , the consumer product selected from a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, and a sign. 12. An organic light emitting device comprising:an anode and a cathode; at least one organic charge transport layer positioned between the anode and the cathode; an organic host layer positioned between the anode and the cathode; and at least two two-dimensional emissive layers positioned within the organic host layer. 13. A consumer product comprising the organic light emitting device of claim 12 , the consumer product selected from a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, and a sign. 14. An organic light emitting device, comprising:a substrate; a first electrode disposed over the substrate; at least one organic layer disposed over the first electrode; a first portion of an organic host layer disposed over the at least one organic layer; at least one two-dimensional emissive layer disposed over the first portion of the organic host layer; a second portion of the organic host layer disposed over the at least one two-dimensional emissive layer; at least one second organic layer disposed over the second portion of the organic host layer; and a second electrode disposed over the at least one two-dimensional emissive layer wherein the at least one two-dimensional emissive layer is a monolayer; and wherein the at least one two-dimensional emissive layer is positioned at a distance of less than 20 nm from a position with the highest density of excitons within the first and second portions of the organic host layer. 15. The organic light emitting device of claim 14 , wherein the two-dimensional emissive layer is selected from a transition metal dichalcogenide (TMD) active layer or an emissive direct bandgap inorganic semiconductor. 16. The organic light emitting device of claim 15 , wherein the TMD active layer is at least one monolayer of WS2. 17. The organic light emitting device of claim 14 , wherein the two-dimensional emissive layer comprises a material selected from at least one monolayer of WS2, Gallium Nitride, a group III-V direct bandgap semiconducting alloy or alloys, or a group II-VI direct bandgap semiconducting alloy or alloys. 18. The organic light emitting device of claim 14 , wherein the first electrode is a transparent anode. 19. The organic light emitting device of claim 14 , wherein the at least one organic layer comprises a hole transport layer and the at least one second organic layer comprises an electron transport layer. 20. A consumer product comprising the organic light emitting device of claim 14 , the consumer product selected from a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, and a sign.
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