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Organic solar cells and methods of making the same

專利號(hào)
US12156413B2
公開(kāi)日期
2024-11-26
申請(qǐng)人
NEW YORK UNIVERSITY; YALE UNIVERSITY
發(fā)明人
Jaemin Kong; Francisco Antonio; Andre Taylor
IPC分類
H10K30/30; H01L31/0236; H01L31/048; H01L31/18; H10K30/20; H10K30/50; H10K30/82
技術(shù)領(lǐng)域
pcbm,p3ht,pristine,in,pbdb,solar,layer,bis,poly,adhesive
地域: NY NY New York

摘要

Described is an active layer having a first surface region and a bulk region, the active layer comprising a small molecule component and a polymer component, wherein the relative concentration of the small molecule component is lower in the first surface than in the bulk region. Also described is a method of producing a surface-modified active layer comprising the steps of providing a pristine active layer comprising a small molecule component and a polymer component; applying an adhesive to the exposed surface of the pristine active layer to produce an adhesive-bound active layer; and removing the adhesive from the adhesive-bound active layer, and a method of producing electrical energy from sunlight, such as sunlight deposited over bodies of water.

說(shuō)明書(shū)

Conversely, however, the electron acceptor is beneficial for the electron donor stability, because the electron acceptor quickly quenches the excited states of the electron donor within several hundred femtoseconds. As a result, the presence of electron acceptor slows down the photo-oxidation progress of electron donor polymer (Reese, et al., Adv. Funct. Mater. 2010, 20 (20), 3476-3483; Hansson, et al., Phys. Chem. Chem. Phys. 2016, 18, 11132-11138; Distler, et al., J. Chem. Mater. 2012, 24 (22), 4397-4405). Thus, in some embodiments, the donor and acceptor components should be well mixed inside the blend film, while on the surface the acceptor component should be minimized in order for electron acceptors to avoid direct contact with oxygen and/or water from the surface.

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