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Organic solar cells and methods of making the same

專利號
US12156413B2
公開日期
2024-11-26
申請人
NEW YORK UNIVERSITY; YALE UNIVERSITY
發(fā)明人
Jaemin Kong; Francisco Antonio; Andre Taylor
IPC分類
H10K30/30; H01L31/0236; H01L31/048; H01L31/18; H10K30/20; H10K30/50; H10K30/82
技術(shù)領(lǐng)域
pcbm,p3ht,pristine,in,pbdb,solar,layer,bis,poly,adhesive
地域: NY NY New York

摘要

Described is an active layer having a first surface region and a bulk region, the active layer comprising a small molecule component and a polymer component, wherein the relative concentration of the small molecule component is lower in the first surface than in the bulk region. Also described is a method of producing a surface-modified active layer comprising the steps of providing a pristine active layer comprising a small molecule component and a polymer component; applying an adhesive to the exposed surface of the pristine active layer to produce an adhesive-bound active layer; and removing the adhesive from the adhesive-bound active layer, and a method of producing electrical energy from sunlight, such as sunlight deposited over bodies of water.

說明書

(0.66 ± 0.01) (7.09 ± 0.2) 1000 0.88 11.3 0.63 6.26 (0.86 ± 0.02) (11.5 ± 0.3) (0.57 ± 0.06) (5.68 ± 0.5) 2000 0.88 10.1 0.51 4.55 (0.87 ± 0.01) (10.0 ± 1) (0.50 ± 0.01) (4.55 ± 0.6)

In summary, the selective removal of the electron acceptor component (e.g., PCBM or non-fullerene acceptor IT-M) from a photoactive blend film surface using a facile tape stripping technique not only minimizes the direct exposure of the electron acceptors to the oxygen or water molecules, but also significantly enhances the adhesion between the photoactive layer and the top electrode. The optimized blend films after the tape stripping exhibits higher durability under harsh ultrasonic conditions and bending stress tests under the water. Moreover, removing the surface electron acceptor component optimizes the blend film morphology in a vertical direction, which results in higher fill factors in the inverted solar cell structure. This approach will initiate a new frontier for the development of highly durable, all-weather organic solar cells that can be operable even under the water.

權(quán)利要求

1
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