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Oxide superconductor and method for manufacturing same

專利號
US12161054B2
公開日期
2024-12-03
申請人
KABUSHIKI KAISHA TOSHIBA(JP Tokyo)
發(fā)明人
Takeshi Araki; Hirotaka Ishii
IPC分類
H10N60/85; H10N60/01
技術領域
ybco,pr,region,in,coating,film,ococh3,oxide,perovskite,μm
地域: Tokyo

摘要

An oxide superconductor of an embodiment includes an oxide superconducting layer including a first superconducting region containing barium, copper, and a first rare earth element, having a continuous perovskite structure, and extending in a first direction, a second superconducting region containing barium, copper, and a second rare earth element, having a continuous perovskite structure, and extending in the first direction, and a non-superconducting region disposed between the first and the second superconducting region, containing praseodymium, barium, copper, and a third rare earth element, a ratio of the number of atoms of the praseodymium to a sum of the number of atoms of the third rare earth element and the number of atoms of the praseodymium which is 20% or more, having a continuous perovskite structure continuous with the perovskite structure of the first superconducting region and the perovskite structure of the second superconducting region, and extending in the first direction.

說明書

The white area on the lower side of FIG. 26 is the LaAlO3 single crystal substrate, and the region in which a slightly black striped pattern appears is the YBCO conductor. The film thickness of the YBCO superconductor is scaled, the thin portion is 223 nm and the thick portion is 301 nm. From the film thickness difference, it can be seen that the sample was formed almost according to the conditions. Although it is difficult to see from FIG. 26, all the striped patterns run in the direction parallel to the substrate. In other words, it shows that the c axis oriented particles are aligned.

FIG. 27 illustrates a TEM image in which the boundary between the LaAlO3 single crystal substrate and the YBCO superconductor in FIG. 26 was observed at a high magnification of 2.17 million times. Each element of the LaAlO3 single crystal substrate can be seen at the bottom of the figure, and the region visible in the lateral stripe pattern is the c axis oriented particle of the YBCO superconductor. As can be seen from FIG. 27, c-axis oriented particles are formed on almost the entire surface, and a portion where stripes are slightly connected in the vertical direction can be seen on the left end of the figure, which is the a/b-axis oriented particle.

權利要求

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