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Oxide superconductor and method for manufacturing same

專利號(hào)
US12161054B2
公開(kāi)日期
2024-12-03
申請(qǐng)人
KABUSHIKI KAISHA TOSHIBA(JP Tokyo)
發(fā)明人
Takeshi Araki; Hirotaka Ishii
IPC分類
H10N60/85; H10N60/01
技術(shù)領(lǐng)域
ybco,pr,region,in,coating,film,ococh3,oxide,perovskite,μm
地域: Tokyo

摘要

An oxide superconductor of an embodiment includes an oxide superconducting layer including a first superconducting region containing barium, copper, and a first rare earth element, having a continuous perovskite structure, and extending in a first direction, a second superconducting region containing barium, copper, and a second rare earth element, having a continuous perovskite structure, and extending in the first direction, and a non-superconducting region disposed between the first and the second superconducting region, containing praseodymium, barium, copper, and a third rare earth element, a ratio of the number of atoms of the praseodymium to a sum of the number of atoms of the third rare earth element and the number of atoms of the praseodymium which is 20% or more, having a continuous perovskite structure continuous with the perovskite structure of the first superconducting region and the perovskite structure of the second superconducting region, and extending in the first direction.

說(shuō)明書

Superconducting characteristics of oxide thin films 1F-low-Pr0.00Y1.00BCO, 1F-low-Pr0.10Y0.90BCO, 1F-high-Pr0.00Y1.00BCO, 1F-high-Pr0.10Y0.90BCO, 1F-high-Pr0.15Y0.85BCO, 1F-high-Pr0.20Y0.80BCO, and 1F-high-Pr0.22Y0.78BCO were each measured by an inductive method in liquid nitrogen under a self-magnetic field. In principle, the superconducting characteristics cannot be evaluated by the inductive method unless the superconductor exists in the region of about 6 mm in diameter in the superconducting film to be targeted. Therefore, the characteristics of only 4 to 6 points in the central portion can be obtained, but the highest value is the characteristic of the superconducting film. The obtained superconducting characteristics each were 6.77, 3.39, 6.81, 3.41, 1.72, 0.00, and 0.00 MA/cm2 (77 K, 0 T).

The measurement results of the superconducting characteristics by the inductive method were based on the result of the 5 times degradation phenomenon, in which the characteristics decreased by about 5 times the amount of Pr added. That is, when 10% of Pr was added, the characteristics were reduced by about 50%, and when 15% of Pr was added, the characteristics were reduced by 75%. It was found that almost the same characteristics were obtained regardless of whether the purity of praseodymium acetate was 98% or 99%, and that the deterioration in characteristics due to the 5 times degradation phenomenon was also almost the same. It was found that the characteristics of those with 20% and 22% of Pr could not be confirmed by the inductive method, and were non-superconducting.

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